He's one of the most famous--and sexiest--men in the world, but Brad Pitt wasn't always the golden boy. This profile looks at the early career struggles that forced Pitt to work at odd jobs to pay for acting lessons. But a breakthrough role on Thelma and Louise put him on the road to superstardom. He famously married Jennifer Aniston, then infamously divorced her to be with Angelina Jolie, which made the couple the paparazzi's No. 1 target. But his fans have forgiven him and Pitt, who supports many humanitarian causes, remains on top of Hollywood's A-list.