She's beautiful, eccentric, highly intelligent and mysterious. The daughter of actor Jon Voight, Angelina hit it big in 1997 when she won critical acclaim and the Best Supporting Actress Emmy for the cable biopic Gia. In hot demand, she moved on to the big screen, winning an Academy Award for Girl Interrupted. She played opposite Denzel Washington in the thriller, The Bone Collector, and starred in the blockbusters Tomb Raider, Gone in Sixty Seconds, and most famously, opposite Brad Pitt in Mr. & Mrs. Smith. A UN goodwill ambassador since 2001, Jolie has put her celebrity behind the fight against poverty in Africa.